| Stage 5: Valencia to Valencia, 149.4km |
| 1. Alessandro Petacchi (Ita) Team Milram | 3:12:54 |
| 2. Danilo Napolitano (Ita) Lampre |
| 3. Francesco Chicchi (Ita) Liquigas |
| 4. Erik Zabel (Ger) Team Milram |
| 5. Rubén Pérez (Spa) Euskaltel-Euskadi |
| 6. JJérôme Pineau (Fra) Bouygues Telecom |
| 7. Javier Benitez (Spa) Benfica |
| 8. Mathieu Drujon (Fra) Caisse d'Epargne |
| 9. Claudio Corioni (Ita) Liquigas |
| 10. Mirco Lorenzetto (Ita) Lampre |
|
| 14. Julian Dean (NZl) Slipstream Chipotle p/b H30 |
| 22. Chris Sutton (Aus) Slipstream Chipotle p/b H30 |
| 29. Trent Lowe (Aus) Slipstream Chipotle p/b H30 |
| 56. Lucas Eusar (USA) Slipstream Chipotle p/b H30 |
| 63. Jonathan McCarty (USA) Slipstream Chipotle p/b H30 |
| 73. Ryder Hesjedal (Can) Slipstream Chipotle p/b H30 |
| 81. Timothy Duggan (USA) Slipstream Chipotle p/b H30 |
| 106. Dan Martin (Irl) Slipstream Chipotle p/b H30 | all s.t. |
|
| Final GC |
| 1. Rubén Plaza (Esp) Benfica | 19:54:49 |
| 2. Manuel Váquez (Esp) Contentpolis - Murcia | at 0:05 |
| 3. Xavier Florencio (Esp) Bouygues Telecom | 0:21 |
| 4. José Iván Gutiérrez (Esp) Caisse d'Epargne | 0:24 |
| 5. Gorka Verdugo (Esp) Euskaltel-Euskadi | 0:31 |
| 6. Alberto Contador (Esp) Astana | 0:33 |
| 7. Jérôme Pineau (Fra) Bouygues Telecom | 0:35 |
| 8. Vincenzo Nibali (Ita) Liquigas |
| 9. Maxime Monfort (Bel) Cofidis |
| 10. Antonio Colom (Esp) Astana |
|
| 11. Trent Lowe (Aus) Slipstream Chipotle p/b H30 | all s.t. |
| 22. Ryder Hesjedal (Can) Slipstream Chipotle p/b H30 | 1:01 |
| 40. Lucas Eusar (USA) Slipstream Chipotle p/b H30 | 7:14 |
| 43. Jonathan McCarty (USA) Slipstream Chipotle p/b H30 | 11:46 |
| 55. Dan Martin (Irl) Slipstream Chipotle p/b H30 | 18:36 |
| 90. Timothy Duggan (USA) Slipstream Chipotle p/b H30 | 33:44 |
| 102. Chris Sutton (Aus) Slipstream Chipotle p/b H30 | 40:20 |
| 107. Julian Dean (NZl) Slipstream Chipotle p/b H30 | 41:03 |
