| Stage 3: La Seu d'Urgell to Asco La Vostra Energia, 217:2km |
| 1. Pierrick Fedrigo (Fra) Bouygues Telecom | 5:06:01 |
| 2. Alexandre Botcharov (Rus) Credit Agricole |
| 3. Gustavo Cesar (Esp) Karpin Galicia |
| 4. Jelle Vanendert (Bel) Francaise des Jeux |
| 5. Daniel Navarro Garcia (Esp) Astana | all s.t. |
| 6. George Hincapie (USA) Team High Road | 0:11 |
| 7. Xavier Florencio Cabre (Esp) Bouygues Telecom |
| 8. Pieter Jacobs (Bel) Silence - Lotto |
| 9. Daniele Righi (Ita) Lampre |
| 10. William Walker (Aus) Rabobank |
|
| 42. Michael Barry (Can) Team High Road | all s.t. |
|
| GC |
| 1. Remi Pauriol (Fra) Credit Agricole | 14:29:33 |
| 2. Haimar Zubeldia Agirre (Esp) Euskaltel - Euskadi | at 0:07 |
| 3. Janez Brajkovic (Slo) Astana | 0:08 |
| 4. Pierrick Fedrigo (Fra) Bouygues Telecom | 0:10 |
| 5. Rigoberto Uran (Col) Caisse d'Epargne | 0:11 |
| 6. Gustavo Cesar (Esp) Karpin Galicia | s.t. |
| 7. Josep Jufre Pou (Esp) Saunier Duval - Scott | 0:12 |
| 8.. Daniel Navarro Garcia (Esp) Astana | 0:21 |
| 9. Daniel Moreno Fernandez (Esp) Caisse d'Epargne | 0:29 |
| 10. Thomas Lovkvist (Swe) Team High Road | s.t. |
|
| 97. Michael Barry (Can) Team High Road | 24:47 |
