| Stage 7: Barbastro to Andorra, 223.2km |
| 1 Alessandro Ballan (Ita) Lampre | 6:15:51 |
| 2 Ezequiel Mosquera (Esp) Xacobeo Galicia | at | 2:42 |
| 3 Alberto Contador (Esp) Astana | 2:45 |
| 4 Joaquin Rodriguez (Esp) Caisse D'Epargne | 2:50 |
| 5 Levi Leipheimer (USA) Astana |
| 6 Igor Anton (Esp) Euskaltel - Euskadi |
| 7 Carlos Sastre (Esp) Team CSC - Saxo Bank | all s.t. |
| 8 Daniel Moreno Fernandez (Esp) Caisse D'Epargne | 3:03 |
| 9 Marzio Bruseghin (Ita) Lampre | 3:11 |
| 10 Davide Rebellin (Ita) Gerolsteiner |
| 11 Robert Gesink (Ned) Rabobank | both s.t. |
| 12 Jurgen Van Goolen (Bel) Team CSC - Saxo Bank | 3:15 |
| 13 Oliver Zaugg (Sui) Gerolsteiner | s.t. |
| 14 Mauricio Ardila (Col) Rabobank | 3:21 |
| 15 Sylvain Chavanel (Fra) Cofidis, le credit par telephone | s.t. |
| 16 Javier Moreno Bazan (Esp) AndalucÃa - Cajasur | 3:39 |
| 17 Inigo Cuesta (Esp) Team CSC - Saxo Bank | s.t. |
| 18 Alberto Losada (Esp) Caisse D'Epargne | 3:40 |
| 19 Alejandro Valverde (Esp) Caisse D'Epargne | s.t. |
| 20 Dominique Cornu (Bel) Silence - Lotto | 3:46 |
| 21 Egoi Martinez (Esp) Euskaltel - Euskadi | 3:48 |
| 22 Gustavo Cesar Veloso (Esp) Xacobeo Galicia | 3:58 |
| 23 Andreas Kloden (Ger) Astana | 4:13 |
| 24 Marc De Maar (Ned) Rabobank | 4:18 |
| 25 David Arroyo (Esp) Caisse D'Epargne | 4:20 |
|
| GC |
| 1 Alessandro Ballan (Ita) Lampre | 23:53:26 |
| 2 Levi Leipheimer (USA) Astana | at 1:00 |
| 3 Sylvain Chavanel (Fra) Cofidis, le credit par telephone | 1:21 |
| 4 Alberto Contador (Esp) Astana | 1:34 |
| 5 Alejandro Valverde (Esp) Caisse D'Epargne | 2:06 |
| 6 Carlos Sastre (Esp) Team CSC - Saxo Bank | 2:27 |
| 7 Jurgen Van Goolen (Bel) Team CSC - Saxo Bank | 2:59 |
| 8 Ezequiel Mosquera (Esp) Xacobeo Galicia | s.t. |
| 9 Igor Anton (Esp) Euskaltel - Euskadi | 3:17 |
| 10 Daniel Moreno Fernandez (Esp) Caisse D'Epargne | 3:23 |
| 11 Marzio Bruseghin (Ita) Lampre | 3:51 |
| 12 Dominique Cornu (Bel) Silence - Lotto | 3:52 |
| 13 Davide Rebellin (Ita) Gerolsteiner | 3:54 |
| 14 Robert Gesink (Ned) Rabobank | 4:11 |
| 15 Joaquin Rodriguez (Esp) Caisse D'Epargne | 5:03 |
| 16 Gustavo Cesar Veloso (Esp) Xacobeo Galicia | 5:04 |
| 17 David Arroyo (Esp) Caisse D'Epargne | 5:24 |
| 18 Egoi Martinez (Esp) Euskaltel - Euskadi | 5:25 |
| 19 Inigo Cuesta (Esp) Team CSC - Saxo Bank | 5:40 |
| 20 Alberto Losada (Esp) Caisse D'Epargne | 6:35 |
| 21 Mauricio Ardila (Col) Rabobank | 6:41 |
| 22 Oliver Zaugg (Sui) Gerolsteiner | 7:11 |
| 23 Andreas Kloden (Ger) Astana | 7:40 |
| 24 Damiano Cunego (Ita) Lampre | 8:24 |
| 25 Juan Manuel Garate (Esp) Quick Step | 9:01 |
